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Beilstein J. Org. Chem. 2016, 12, 564–570, doi:10.3762/bjoc.12.55
Graphical Abstract
Scheme 1: Selected examples of oligopeptides bearing dehydroamino acid moieties: myxovalargin (1), argyrin A (...
Scheme 2: The Buchwald cross-coupling reaction in the preparation of peptides containing dehydroamino acids 4....
Scheme 3: Syntheses of vinyl iodides 10 and 11.
Scheme 4: Preparation of vinyl iodides 24–29 (Cbz = benzyloxycarbonyl, Alloc = allyloxycarbonyl, Boc = tert-b...
Scheme 5: Copper-mediated C–N cross-coupling of dehydropeptides 31–33, 36, 37, and 39–41.
Scheme 6: C–N coupling reaction between amide 43 and vinyl iodide 42; formation of dehydroisoleucine containi...